I recently got my ZFold3 device. After migrating from my S10, I noticed that the VoLTE button in the Quick Panel disappeared. The VoLTE function does not seem to work despite having it turned on in the Mobile Networks setting. Has anyone encountered this?
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As for your concern, try to follow the steps provided on the link below on how to set up your device for VoLTE use.
Stumbled upon this post because my Fold 3 simply doesn't show Volte option. Followed your instructions in this post, and I just get a different screen without Volte.
Since you just got the phone set up you may need to manually register the phone to your network. In this way, your network provider will be notified of your phone's IMEI.
Head to Settings >> Connections >> Mobile networks >> Network operators >> Turn off the Select automatically toggle switch. Your phone will scan for available networks and once your network provider appeared, select it to initiate manual registration.
If doing that will not give a difference, try resetting the phone's APN settings. Just head to Settings >> Connections >> Mobile networks >> 3 dot menu at the upper right >> Reset to default.
If all the suggested steps above will not fix the problem, try changing your network mode in Settings >> Connections >> Mobile networks >> Network mode.
